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(i) NO2- ⇒ 2σ + 1 lp =3, ie, sp2 hybridisation(ii) NH3 ⇒ 3σ + 1 lp = 4, ie, sp3 hybridisation(iii) BF3 ⇒ 3σ + 0 lp = 3, i.e sp2 hybridisation(iv) NH2- ⇒ 2σ + 2 lp = 4 i.e sp3 hybridisation(v) H2O ⇒ 2σ + 2 lp = 4 i.e sp3 hybridisationThus, among the given pairs, only BF3 and NO2- have sp2 hybridizations.